Multicomponent Distillation - Mathematical Modeling, Global Optimization, and Process Intensication
2019-01-03T16:05:44Z (GMT) by
Distillation is the most important separation process that accounts for 90-95% of all separations in the chemical industries. Even slight improvements can tremendously impact the landscape of the chemical economy world. The goal of this thesis is to develop mathematical modeling and global optimization approaches as well as systematic process intensication strategies to design and synthesize compact, easy-to-operate, energy-efficient, and cost-effective multicomponent distillation systems.
Towards this goal, we discuss the following aspects in this thesis:
1. We solve a longstanding challenge in chemical engineering of developing a short-cut method to determine the minimum reflux condition for any multi-feed, multi-product distillation column separating ideal multicomponent mixtures. The classic Underwood's method turns out to be a special case of our approach.
2. We develop the rst enumeration based global optimization algorithm to identify optimal distillation congurations that can potentially save up to 50% of total cost or total exergy loss compared to conventional schemes from the immense conguration search space. For the first time in the literature, global optimality is guaranteed.
3. We propose a systematic and comprehensive multi-layer approach for process intensication in multicomponent distillation. For the first time, industrial practitioners have an easy-to-follow recipe to generate an array of completely new and attractive highly intensied conguration designs that further enhance operability, improve efficiency, and reduce total costs.